Among the early families were Buchanan, Couch, Crockett, Duff, King, Morris, Paschall, Price, Roberts, and Sayers.

The original store and post office were on the west corner of Wilson Pike and Murfreesboro Road.

As early as 1804 Peter Cartwright, William McKendree, and Jacob Young were preaching the Methodist doctrine in southeastern Williamson County.

In 1849, the congregation moved to a larger building, located just north of Triune, where the original cornerstone of Kings' Chapel is prominently displayed above the front door.

The Union Army occupied the abandoned church during the Civil War, which became a dairy barn in the 20th Century.