Relative atomic mass

Additionally, the continued use of the term "atomic weight" (for any element) as opposed to "relative atomic mass" has attracted considerable controversy since at least the 1960s, mainly due to the technical difference between weight and mass in physics.

Relative atomic mass is therefore a more general term that can more broadly refer to samples taken from non-terrestrial environments or highly specific terrestrial environments which may differ substantially from Earth-average or reflect different degrees of certainty (e.g., in number of significant figures) than those reflected in standard atomic weights.

[14][15] Nevertheless, given the cost and difficulty of isotope analysis, it is common practice to instead substitute the tabulated values of standard atomic weights, which are ubiquitous in chemical laboratories and which are revised biennially by the IUPAC's Commission on Isotopic Abundances and Atomic Weights (CIAAW).

[16] Older (pre-1961) historical relative scales based on the atomic mass unit (symbol: a.m.u.

See the article on the history of the modern unified atomic mass unit for the resolution of these problems.

Standard atomic weight requires the sources be terrestrial, natural, and stable with regard to radioactivity.

These values are widely published and referred to loosely as 'the' atomic weight of elements for real-life substances like pharmaceuticals and commercial trade.

Modern relative atomic masses (a term specific to a given element sample) are calculated from measured values of atomic mass (for each nuclide) and isotopic composition of a sample.

The calculation is exemplified for silicon, whose relative atomic mass is especially important in metrology.

The calculation is as follows: The estimation of the uncertainty is complicated,[21] especially as the sample distribution is not necessarily symmetrical: the IUPAC standard relative atomic masses are quoted with estimated symmetrical uncertainties,[22] and the value for silicon is 28.0855(3).

To reflect this natural variability, the IUPAC made the decision in 2010 to list the standard relative atomic masses of 10 elements as an interval rather than a fixed number.