Fourth-seeded Tayfur Aliyev scored a round-of-16 victory to secure a spot in the men's featherweight division at the 2020 European Qualification Tournament in London, United Kingdom.

Anna Bashta claimed a spot in the women's sabre by winning the final match at the European Zonal Qualifier in Madrid, Spain.

İvan Tixonov and Marina Nekrasova received a spare berth each from the men's and women's apparatus events, respectively, as one of the highest-ranked gymnasts, neither part of the team nor qualified directly through the all-around, at the 2019 World Championships in Stuttgart, Germany.

Rio 2016 Olympian Milad Beigi qualified directly for the second time in the men's welterweight category (80 kg) by finishing among the top five taekwondo practitioners at the end of the WT Olympic Rankings.

Meanwhile, two-time Olympian Farida Azizova scored a semifinal victory in the women's welterweight category (67 kg) to book the remaining spot on the Azerbaijani taekwondo squad at the 2021 European Qualification Tournament in Sofia, Bulgaria.