The Burgess reagent (methyl N-(triethylammoniumsulfonyl)carbamate) is a mild and selective dehydrating reagent often used in organic chemistry.
[1][2] It was developed in the laboratory of Edward M. Burgess at Georgia Tech.
The Burgess reagent is used to convert secondary and tertiary alcohols with an adjacent proton into alkenes.
The reagent is soluble in common organic solvents and alcohol dehydration takes place with syn elimination through an intramolecular elimination reaction.
The reagent is prepared from chlorosulfonylisocyanate by reaction with methanol and triethylamine in benzene:[3]