Center Valley is a small unincorporated residential and agricultural community in the town of Center, Outagamie County, Wisconsin, United States.

Center Valley lies 5 miles (8.0 km) north of the City of Appleton, and is served by the post office of Black Creek, which has the ZIP code 54106.

Center Valley is located at 44°24′8″N 88°27′35″W / 44.40222°N 88.45972°W / 44.40222; -88.45972 (44.4022079, -88.4598254), and the elevation is 820 feet (250 m).

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