Kempenaers-Pocz made her WTA Tour debut at the 2021 Yarra Valley Classic in the doubles, partnering Jaimee Fourlis after receiving a wild card into the main draw.

[2] Kempenaers-Pocz was introduced to tennis at age five by her parents[1] Kempenaers-Pocz made her ITF Women's World Tennis Tour main draw debut in Port Pirie in February 2019, where she reached the semi-final as a 14-year-old.

[3][4] In January 2021, Kempenaers-Pocz lost in the first round of the 2021 Australian Open – Women's singles qualifying.

[5] In January 2022, Kempenaers-Pocz lost in the first round of the 2022 Australian Open – Women's singles qualifying.

[6] Only main-draw results in WTA Tour, Grand Slam tournaments, Fed Cup and Olympic Games are included in win–loss records.