Chemotrophs can be found in areas where electron donors are present in high concentration, for instance around hydrothermal vents.
Most chemoautotrophs are prokaryotic extremophiles, bacteria, or archaea that live in otherwise hostile environments (such as deep sea vents) and are the primary producers in such ecosystems.
Chemoautotrophs generally fall into several groups: methanogens, sulfur oxidizers and reducers, nitrifiers, anammox bacteria, and thermoacidophiles.
[2][3] The term "chemosynthesis", coined in 1897 by Wilhelm Pfeffer, originally was defined as the energy production by oxidation of inorganic substances in association with autotrophy — what would be named today as chemolithoautotrophy.
[10] Iron has many existing roles in biology not related to redox reactions; examples include iron–sulfur proteins, hemoglobin, and coordination complexes.
Microbiology of a Sediment Pond and the Underlying Young, Cold, Hydrologically Active Ridge Flank.