Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic anthophyllite, which is a much more common form of magnesium-rich amphibole, the latter being metastable.

[3] Cummingtonite is a member of the cummingtonite-grunerite solid solution series which ranges from Mg7Si8O22(OH)2 for magnesiocummingtonite to the iron rich grunerite endmember Fe7Si8O22(OH)2.

These minerals are found in high-grade metamorphic banded iron formation and form a compositional series between Mn2Mg5Si8O22(OH)2 (tirodite) and Mn2Fe5Si8O22(OH)2 (dannemorite).

Amosite is a rare asbestiform variety of grunerite that was mined as asbestos only in the eastern part of the Transvaal Province of South Africa.

The grunerite end member is characteristic of the metamorphosed iron formations of the Lake Superior region and the Labrador Trough.