Cyclopentadienylmolybdenum tricarbonyl dimer is the chemical compound with the formula Cp2Mo2(CO)6, where Cp is C5H5.
A dark red solid, it has been the subject of much research although it has no known practical uses.
[1] The six CO ligands are terminal and the Mo-Mo bond distance is 3.2325 Å.
[2] The compound is prepared by treatment of molybdenum hexacarbonyl with sodium cyclopentadienide followed by oxidation of the resulting NaMo(CO)3(C5H5).
[4] Thermolysis of this compound in hot solution of diglyme (bis(2-methoxyethyl)ether) results in decarbonylation, giving the tetracarbonyl,[4] which has a formal triple bond between the Mo centers (dMoMo = 2.448 Å):[5] The resulting cyclopentadienylmolybdenum dicarbonyl dimer in turn binds a variety of substrates across the metal-metal triple bond.