Molybdocene dichloride is the organomolybdenum compound with the formula (η5-C5H5)2MoCl2 and IUPAC name dichlorobis(η5-cyclopentadienyl)molybdenum(IV), and is commonly abbreviated as Cp2MoCl2.
The compound is prepared from molybdocene dihydride by treatment with chloroform:[2] The compound adopts a "clamshell" structure where the Cp rings are not parallel, the average Cp(centroid)-M-Cp angle being 130.6°.
This trend helped to establish the orientation of the HOMO in this class of complex.
[3] Unlike the titanocene and zirconacene derivatives, the molybdocene compounds have yielded no commercial applications.
All metallocene dihalides exhibit some anti-cancer activity,[4] but these have not yielded useful compounds in the clinic.