Diamond

Diamond has the highest hardness and thermal conductivity of any natural material, properties that are used in major industrial applications such as cutting and polishing tools.

Much more recently (hundreds to tens of million years ago), they were carried to the surface in volcanic eruptions and deposited in igneous rocks known as kimberlites and lamproites.

Synthetic diamonds can be grown from high-purity carbon under high pressures and temperatures or from hydrocarbon gases by chemical vapor deposition (CVD).

[4][5] Tetrahedra are rigid, the bonds are strong, and, of all known substances, diamond has the greatest number of atoms per unit volume, which is why it is both the hardest and the least compressible.

[15] Results published in Nature Physics in 2010 suggest that, at ultra-high pressures and temperatures (about 10 million atmospheres or 1 TPa and 50,000 °C), diamond melts into a metallic fluid.

As diamond's crystal structure has a cubic arrangement of the atoms, they have many facets that belong to a cube, octahedron, rhombicosidodecahedron, tetrakis hexahedron, or disdyakis dodecahedron.

The hardest natural diamonds mostly originate from the Copeton and Bingara fields located in the New England area in New South Wales, Australia.

Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness.

[44][45] Thin needles of diamond can be made to vary their electronic band gap from the normal 5.6 eV to near zero by selective mechanical deformation.

However, when diamond surfaces are chemically modified with certain ions, they are expected to become so hydrophilic that they can stabilize multiple layers of water ice at human body temperature.

[59] In order of increasing rarity, yellow diamond is followed by brown, colorless, then by blue, green, black, pink, orange, purple, and red.

[64] Between 25% and 35% of natural diamonds exhibit some degree of fluorescence when examined under invisible long-wave ultraviolet light or higher energy radiation sources such as X-rays and lasers.

Diamonds can fluoresce in a variety of colors including blue (most common), orange, yellow, white, green and very rarely red and purple.

[68] In addition, diamonds in the Wawa belt of the Superior province in Canada and microdiamonds in the island arc of Japan are found in a type of rock called lamprophyre.

In modern searches, geophysical methods such as aeromagnetic surveys, electrical resistivity, and gravimetry, help identify promising regions to explore.

[68] Another common source that does keep diamonds intact is eclogite, a metamorphic rock that typically forms from basalt as an oceanic plate plunges into the mantle at a subduction zone.

The characteristic pattern in diamonds from the lithosphere involves a nearly concentric series of zones with very thin oscillations in luminescence and alternating episodes where the carbon is resorbed by the fluid and then grown again.

[68] Geological evidence supports a model in which kimberlite magma rises at 4–20 meters per second, creating an upward path by hydraulic fracturing of the rock.

In the 20th century, experts in gemology developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem.

The WFDB consists of independent diamond bourses in major cutting centers such as Tel Aviv, Antwerp, Johannesburg and other cities across the US, Europe and Asia.

The recent expansion of this industry in India, employing low cost labor, has allowed smaller diamonds to be prepared as gems in greater quantities than was previously economically feasible.

[130] Roughly 49% of diamonds originate from Central and Southern Africa, although significant sources of the mineral have been discovered in Canada, India, Russia, Brazil, and Australia.

[125] They are mined from kimberlite and lamproite volcanic pipes, which can bring diamond crystals, originating from deep within the Earth where high pressures and temperatures enable them to form, to the surface.

Today, diamonds are located in the diamond-rich density fraction with the help of X-ray fluorescence, after which the final sorting steps are done by hand.

Australia boasts the richest diamantiferous pipe, with production from the Argyle diamond mine reaching peak levels of 42 metric tons per year in the 1990s.

This is done by requiring diamond-producing countries to provide proof that the money they make from selling the diamonds is not used to fund criminal or revolutionary activities.

[67] It is possible to make colorless synthetic gemstones that, on a molecular level, are identical to natural stones and so visually similar that only a gemologist with special equipment can tell the difference.

It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them into chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch, or laser.

[161] Diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could be found many centuries ago along the rivers Penner, Krishna, and Godavari.

[162][163] The popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.

Main diamond producing countries
Theoretically predicted phase diagram of carbon
Diamond unit cell, showing the tetrahedral structure
A triangular facet of a crystal having triangular etch pits with the largest having a base length of about 0.2 millimetres (0.0079 in)
One face of an uncut octahedral diamond, showing trigons (of positive and negative relief) formed by natural chemical etching
The extreme hardness of diamond in certain orientations makes it useful in materials science, as in this pyramidal diamond embedded in the working surface of a Vickers hardness tester .
Picture of a diamond
The most famous colored diamond, the Hope Diamond
Necklace of rough light brown diamonds under UV light (top) and normal light (bottom)
Geologic provinces of the world. The pink and orange areas are shields and platforms , which together constitute cratons.
Diavik Mine , on an island in Lac de Gras in northern Canada
Eclogite with centimeter-size garnet crystals
Red garnet inclusion in a diamond [ 76 ]
Age zones in a diamond [ 76 ]
Diagram of a volcanic pipe
A clear faceted gem supported in four clamps attached to a wedding ring
A round brilliant cut diamond set in a ring
Diamond polisher in Amsterdam
A large rectangular pink multifaceted gemstone, set in a decorative surround. The decoration includes a row of small clear faceted gemstones around the main gem's perimeter, and clusters of gems forming a crest on one side. The crest comprises a three-pointed crown faced by two unidentifiable animals.
The Daria-i-Noor Diamond—an example of unusual diamond cut and jewelry arrangement.
Diamond balance scale 0.01–25 carat jeweler's measuring tool
A diamond scalpel consisting of a yellow diamond blade attached to a pen-shaped holder
A scalpel with synthetic diamond blade
A polished metal blade embedded with small diamonds
Close-up photograph of an angle grinder blade with tiny diamonds shown embedded in the metal
A diamond knife blade used for cutting ultrathin sections (typically 70 to 350 nm) for transmission electron microscopy
Siberia 's Udachnaya diamond mine
A clear octahedral stone protrudes from a black rock
The slightly misshapen octahedral shape of this rough diamond crystal in matrix is typical of the mineral. Its lustrous faces also indicate that this crystal is from a primary deposit
Unsustainable diamond mining in Sierra Leone. Documentary as part of the Vrinda Project for Wikibooks
A round sparkling, clear gemstone with many facets.
Gem-cut synthetic silicon carbide set in a ring