Diamond has the highest hardness and thermal conductivity of any natural material, properties that are used in major industrial applications such as cutting and polishing tools.
Much more recently (hundreds to tens of million years ago), they were carried to the surface in volcanic eruptions and deposited in igneous rocks known as kimberlites and lamproites.
Synthetic diamonds can be grown from high-purity carbon under high pressures and temperatures or from hydrocarbon gases by chemical vapor deposition (CVD).
[4][5] Tetrahedra are rigid, the bonds are strong, and, of all known substances, diamond has the greatest number of atoms per unit volume, which is why it is both the hardest and the least compressible.
[15] Results published in Nature Physics in 2010 suggest that, at ultra-high pressures and temperatures (about 10 million atmospheres or 1 TPa and 50,000 °C), diamond melts into a metallic fluid.
As diamond's crystal structure has a cubic arrangement of the atoms, they have many facets that belong to a cube, octahedron, rhombicosidodecahedron, tetrakis hexahedron, or disdyakis dodecahedron.
The hardest natural diamonds mostly originate from the Copeton and Bingara fields located in the New England area in New South Wales, Australia.
Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness.
[44][45] Thin needles of diamond can be made to vary their electronic band gap from the normal 5.6 eV to near zero by selective mechanical deformation.
However, when diamond surfaces are chemically modified with certain ions, they are expected to become so hydrophilic that they can stabilize multiple layers of water ice at human body temperature.
[59] In order of increasing rarity, yellow diamond is followed by brown, colorless, then by blue, green, black, pink, orange, purple, and red.
[64] Between 25% and 35% of natural diamonds exhibit some degree of fluorescence when examined under invisible long-wave ultraviolet light or higher energy radiation sources such as X-rays and lasers.
Diamonds can fluoresce in a variety of colors including blue (most common), orange, yellow, white, green and very rarely red and purple.
[68] In addition, diamonds in the Wawa belt of the Superior province in Canada and microdiamonds in the island arc of Japan are found in a type of rock called lamprophyre.
In modern searches, geophysical methods such as aeromagnetic surveys, electrical resistivity, and gravimetry, help identify promising regions to explore.
[68] Another common source that does keep diamonds intact is eclogite, a metamorphic rock that typically forms from basalt as an oceanic plate plunges into the mantle at a subduction zone.
The characteristic pattern in diamonds from the lithosphere involves a nearly concentric series of zones with very thin oscillations in luminescence and alternating episodes where the carbon is resorbed by the fluid and then grown again.
[68] Geological evidence supports a model in which kimberlite magma rises at 4–20 meters per second, creating an upward path by hydraulic fracturing of the rock.
In the 20th century, experts in gemology developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem.
The WFDB consists of independent diamond bourses in major cutting centers such as Tel Aviv, Antwerp, Johannesburg and other cities across the US, Europe and Asia.
The recent expansion of this industry in India, employing low cost labor, has allowed smaller diamonds to be prepared as gems in greater quantities than was previously economically feasible.
[130] Roughly 49% of diamonds originate from Central and Southern Africa, although significant sources of the mineral have been discovered in Canada, India, Russia, Brazil, and Australia.
[125] They are mined from kimberlite and lamproite volcanic pipes, which can bring diamond crystals, originating from deep within the Earth where high pressures and temperatures enable them to form, to the surface.
Today, diamonds are located in the diamond-rich density fraction with the help of X-ray fluorescence, after which the final sorting steps are done by hand.
Australia boasts the richest diamantiferous pipe, with production from the Argyle diamond mine reaching peak levels of 42 metric tons per year in the 1990s.
This is done by requiring diamond-producing countries to provide proof that the money they make from selling the diamonds is not used to fund criminal or revolutionary activities.
[67] It is possible to make colorless synthetic gemstones that, on a molecular level, are identical to natural stones and so visually similar that only a gemologist with special equipment can tell the difference.
It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them into chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch, or laser.
[161] Diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could be found many centuries ago along the rivers Penner, Krishna, and Godavari.
[162][163] The popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.