It was because of Vuk that he began collecting Serbian national folk songs in the region of Banat.

It was at the time he began writing several scholastic textbooks, including a German Grammar for Serbian youth.

Also, Tirol prepared a Serbian grammar that Vuk Karadžić included in the Srpski rječnik for Jacob Grimm who published his Wuk's Stephanowitsch kleine Serbische Grammatik in 1824.

[4] In 1827 he published his Slavenska gramatika, sad prvi red na srpskom jeziku (Volume 1).

[5] In 1828, Dimitrije P. Tirol founded the Serbian Literary Society of Timişoara with Pavel Kengelac and Đorđe Čokrljan.

[7] In 1839, Dimitrije, as Miloš's teacher (son of Prince Jevrem Obrenović, was sent to Imperial Russia.