From 1992 to 2001, he was a member of the Parni iz Baku team of the Russian TV show KVN.

He studied at the Azerbaijan State University of Culture and Arts and obtained his diploma as a movie stage director.

He continued his studies at the opera studio at the Baku Music Academy (with Azad Aliyev, conductor), and at the Mozarteum University in Salzburg (with Richard Miller and Alessandro Misciasci).

[2] Thereafter, he was a member of Galina Vishnevskaya's Opera Centre in Moscow, with Badri Maisuradze.

Azizov is the winner of the 2nd Prize of The International Opera Singers Contest of Galina Vishnevskaya (2008), and the 4th Prize of The International Opera Singers Contest of Bulbul in Baku (2005).