Verneuil method

It is primarily used to produce the ruby, sapphire and padparadscha varieties of corundum, as well as the diamond simulants rutile, strontium titanate and spinel.

[2][3] Since the study of alchemy began, there have been attempts to synthetically produce precious stones, and ruby, being one of the prized cardinal gems, has long been a prime candidate.

By 1877, chemist Edmond Frémy had devised an effective method for commercial ruby manufacture by using molten baths of alumina, yielding the first gemstone-quality synthetic stones.

One of Verneuil's sources of inspiration for developing his own method was the appearance of synthetic rubies sold by an unknown Genevan merchant in 1880.

The most notable improvements in the process were made in 1932, by S. K. Popov, who helped establish the capability for producing high-quality sapphires in the Soviet Union through the next 20 years.

A large production capability was also established in the United States during World War II, when European sources were not available, and jewels were in high demand for their military applications such as for timepieces.

Despite some improvements in the method, the Verneuil process remains virtually unchanged to this day, while maintaining a leading position in the manufacture of synthetic corundum and spinel gemstones.

[4] But because the bauxite from which alumina is obtained is most likely by way of the Bayer process (the first stage of which introduces caustic soda in order to separate the Al2O3) particular attention must be paid to the feedstock.

Crystals produced by the Verneuil process are chemically and physically equivalent to their naturally occurring counterparts, and strong magnification is usually required to distinguish between the two.

Another distinguishing feature is the common presence of microscopic gas bubbles formed due to an excess of oxygen in the furnace; imperfections in natural crystals are usually solid impurities.

A sketch of an early furnace used by Verneuil to synthesise rubies using the Verneuil process.
A simplified diagram of the Verneuil process
A small ruby boule, still attached to the rod, produced by the Verneuil process
Synthetic Corundum