Henrietta Alexandrine Friederike Wilhelmine of Nassau-Weilburg, then of Nassau (areas now part of Germany) (30 October 1797 Palace Eremitage, Bayreuth – 29 December 1829, Vienna) was the wife of Archduke Charles, Duke of Teschen.

Her maternal grandparents were Buggraf Georg Wilhelm von Kirchberg, Count of Sayn-Wittgenstein-Hachenburg (1751-1777) and his wife, Princess Isabelle Auguste Reuss of Greiz (1752-1824).

Her paternal grandparents were Karl Christian of Nassau-Weilburg and Princess Wilhelmine Carolina of Orange-Nassau, both members of the different branches of an ancient House of Nassau.

Anne was in turn the second child and eldest daughter of King George II of Great Britain and his wife, Margravine Caroline of Brandenburg-Ansbach.

However he had been adopted and raised by his childless, but rich aunt, Archduchess Marie Christine of Austria and her husband Prince Albert of Saxony, Duke of Teschen.