The album includes guest appearances by Joan Jett, Beth Ditto, Josh Homme, Samantha Maloney, Mocky and her one-time roommate Feist.

Early sessions of Impeach My Bush were recorded at Peaches' Berlin studio with Eagles of Death Metal singer Jesse "The Devil" Hughes.

She finished recording the album with producers Mickey Petralia[1] and Greg Kurstin at Jeff Porcaro's (Toto) self-built studio in Los Angeles.

[3] Lyrically, Impeach My Bush continues the explicit references, double entendres, and gender politics of Peaches' two previous albums.

In addition, "You Love It" was played at the ending of the CSI: NY season three episode "Oedipus Hex" on October 18, 2006, and "Tent in Your Pants" was used in the 2007 comedy film Young People Fucking.

[3] Likewise, Tony Naylor of the NME commented that the album "is no great sonic leap forward, but it is a near-perfect distillation of Peaches' 'thing'.