He was the son of John Edwards of Belvedere House, Lambeth, Surrey, who had bought an estate in the Neath valley and built Rheola House to a design by John Nash.
[3] Edwards-Vaughan married twice: firstly Ann, the daughter and heiress of Thomas Williams of Court Herbert, Glamorgan and secondly Sarah, the daughter and heiress of Daniel Parkin and his wife Sarah Barwis of London, and widow of James Dalton of Russell Square, Middlesex, with whom he had a son and a daughter.
Their daughter Jessie married his fellow MP at Wells, John Lee Lee and their son Vaughan Hanning Vaughan-Lee sat as an MP after serving in the Crimean War.
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