He played college football at Alabama and was selected by the Cincinnati Bengals in the first round of the 2019 NFL draft.

[8] On June 25, 2019, it was revealed that Williams underwent left shoulder surgery to repair a torn labrum.

[12] Following the Bengals signing left tackle Orlando Brown Jr., Williams requested a trade in March 2023.

[14] He was named the starting right tackle in Week 1, but suffered a knee injury in the game and was placed on injured reserve on September 11.

During the Cardinals' Week 15 win over the New England Patriots on December 15, 2024, Williams recovered a fumble by Greg Dortch in the end zone for his first career touchdown.