The first students were housed in a one-room log structure that lasted until 1870 when it was burned to the ground as a result of lightning.

In 1886 Liberty Center Schools constructed a three-story brick building initially to house all grades and would undergo multiple renovations and expansion in 1925 and 1937.

In 1996, as a result of growing enrollment and district population, Liberty Center Local Schools completed a new junior high structure to house grades 6-8 which included a new multi-purpose gymnasium and lobby/cafeteria which also connected the high school building to the elementary building.

In May 2015 voters approved of a $42 million levy to construct a new two-storied K-12 building which was completed and opened in January 2018.

[4] Liberty Center is a charter member of the Northwest Ohio Athletic League (NWOAL), having been formed in 1926.