Live in Hollywood was recorded on RBD's first concert in Los Angeles, California on January 21, 2006, at the Pantages Theatre, as part of the group's 'Tour Generación 2006' world tour.

The acoustic music that appears on the album was recorded live, though in a way posing a different style to the group's previous Tour Generación RBD En Vivo.

On April 19, 2006, the first single off the album was released, a new song titled "No Pares", which was sung solely by Dulce María.

The song was written by former Mexican pop star Lynda Thomas and producer Carlos Lara.

The show itself had a visually colorful and acoustic style, even counting with the support of a gospel choir.

One of the members of RBD, Christian Chávez, explained during an interview that the songs recorded belonged to the Nuestro Amor album, the difference being that this time the songs were acoustic, and added: "There are many instruments, strings, percussions, and the finished product is something very cool, more intimate".

The album was simultaneously put on sale on April 4, 2006, in Mexico, Brazil, and the United States.

[2] The release is mostly composed of the songs included in RBD's second studio album, Nuestro Amor.