The song, inspired by a remark Stills heard from musician Billy Preston, became his biggest hit single, peaking at No.

The song was later recorded by various artists including the Isley Brothers, The Meters, Bucks Fizz, Luther Vandross and Bob Seger.

"[2] Cash Box said that Stills's "unique melodic work, the harmonies and a booming rhythm track make this a bright attraction for top forty as well as FM playlists.

"[3] Record World said that "Stills shines with the help of some fine background singers and his vocal style is exemplary, as usual.

[19] In a review, music magazine Number One said that the song lacked bass and sounded rather "tinny" but predicted that it would be a hit.

A second 12" single was released featuring a dance edit of "Love the One You're With", backed by another alternate mix of "I Hear Talk".

"[30] Dennis Hunt from Los Angeles Times felt Vandross "gives a leaden feel to the normally joyous "Love the One You're With", undercutting a breezy, gospel-style arrangement.

"[31] Pan-European magazine Music & Media commented, "Hailed the King of silky ballads, Luther also knows how to speed it up.

Idris Elba, playing Janek, sings a short phrase from the song after claiming his squeezebox once belonged to Stephen Stills.