He was also a regular member of both the British and, at the Commonwealth Games, English 4 x 100-metre sprint relay teams, to some considerable success.

There Devonish, along with Jason Gardener, Darren Campbell and Mark Lewis-Francis, won a gold medal in the 4x100m.

relay, where the quartet defeated the pre-race favourites, United States team, by just 0.01 seconds, in a season's best of 38.07.

For the 2007 season Devonish improved his performance in the 100 m with a new personal best and competed in this event at the 2007 World Championships in Osaka rather than the 200 m which he had previously specialised in.

[5] On 22 August 2009, Devonish was a member of the Great Britain and Northern Ireland men's 4x100m relay team that took bronze at the IAAF World Championships in Berlin with a season's best of 38.02.