Like other SAFT equations of state, it makes use of chain and association terms developed by Chapman, et al from perturbation theory.
[1] However, unlike earlier SAFT equations of state that used unbonded spherical particles as a reference fluid, it uses spherical particles in the context of hard chains as reference fluid for the dispersion term.
[2] PC-SAFT was developed by Joachim Gross and Gabriele Sadowski, and was first presented in their 2001 article.
[2] Further research extended PC-SAFT for use with associating and polar molecules, and it has also been modified for use with polymers.
[7][8] The equation of state is organized into terms that account for different types of intermolecular interactions, including terms for The equation is most often expressed in terms of the residual Helmholtz energy because all other thermodynamic properties can be easily found by taking the appropriate derivatives of the Helmholtz energy.