The route progresses to the southeast, quickly intersecting with Tennessee Gas Road, where the roadway begins its rural settings.

The highway makes a curve to the northeast after Spencer Hill Road intersects, where it enters Granville Township.

[2] PA 514 then enters Granville Center, a small hamlet, which stretches until the intersection with Baileys Corners Road (State Route 3019 or SR 3019).

After Baileys Corners Road, PA 514 continues eastward until turning to the southeast once again, maintaining its rural surroundings.

[4] The rest of the alignment, from Granville Center to PA 414 in West Franklin, was still under construction until 1934, when the route was opened to traffic.