Photoferroelectric imaging

One type of medium which has been used for photoferroelectric imaging is lead lanthanum zirconate titanate (PLZT) ceramics,[1] which exhibit a good combination of properties for imaging: large electro-optic coefficients, high intrinsic and extrinsic photosensitivities, and nonvolatile memory.

[3] A description of a photoferroelectric imaging process (using PLZT material) is given in the McGraw-Hill Concise Encyclopedia of Science and Technology.

In that process, a thin flat plate of transparent, optically polished PLZT material (around 0.25mm thick) was sputter-coated with indium tin oxide (ITO) on both sides, serving as electrodes.

The ferroelectric polarization thereby switched from one remanent state to another, and images were "stored both as spatial distributions of light-scattering centers in the bulk of the PLZT and as surface deformation strains which form a relief pattern of the image on the exposed surface.

In the example process, the ceramic was poled[a] to a saturation remanent polarization state by the light (charge carriers were photoexcited across the PLZT's bandgap).