Polymethine dyes

general structure of hemicyanine dyesIf both terminal amino and imino groups of the chromophore are open chain, one speaks of streptocyanine dyes.

[6] general structure of merocyanine dyesMembers of the oxonol dyes, whose terminal groups contain oxygen as heteroatom, play a role in analogue colour photography[8] and the following of enzymatic reactions via the use of barbituric and thiobarbituric terminal groups.

[9][10] general structure of oxonol dyesBy condensing an active methylene compound (e.g. malonic acid dinitrile) with a benzaldehyde derivative, styryl dyes are obtained.

By integrating a benzene ring into the polyene part, these compounds have a styrene partial structure.

Disperse Yellow 31 (3)Also amino- and hydroxy-substituted di- and triarylmethines comprise the structural element of a methine dye: Triarylmethine dyes, resonance structure (R=H, alkyl)Triarylmethine dyes are derived from triphenylmethane, in which at least two of the aromatic rings have electron-donating substituents (e.g. amino groups, secondary and tertiary alkylamino groups or hydroxy groups).

58 Triarylmethine dyes usually show intensive, luminous colourings with different light fastness.

Example: C.I. Basic Red 12 [ 4 ]
Example: C.I. Basic Yellow 11 [ 5 ]
Example: Oxonol Blau [ 7 ]
General structure of quinonimine dyes where X = OH, NH 2 or NR 2 Y = O or NH