Following the 1812 Constitution, the first deputation should have convened on 14 August 1813, although there are no records of meetings for such period neither for the Trienio Liberal.

[2][3] Santiago Villa, from Torrijos, became the first president of the provincial corporation.

The partisan distribution of the plenary is determined as per the D'Hondt apportionment of the results of the sum of municipal elections in each one of the judicial districts (as of 2019: Toledo, Talavera de la Reina, Torrijos, Quintanar de la Orden, Orgaz and Ocaña).

[6] The president of the deputation is elected by the plenary from among its members at the constitutive session of the provincial corporation that follows the constitutive session of the municipal corporations (the ayuntamientos).

[7] Since 2015, Álvaro Gutiérrez Prieto [es] (Mayor of Escalona and member of the Spanish Socialist Workers' Party), serves as president of the provincial deputation.