[1] When the coenzyme S-adenosylmethionine (SAM) is used in a methylation reaction, SAH is produced.
SAH riboswitches typically up-regulate genes involved in recycling SAH to create more SAM (or the metabolically related methionine).
This is particularly relevant to cells, because high levels of SAH can be toxic.
[2] Originally identified by bioinformatics,[3] SAH riboswitches are apparent in many species of bacteria, predominantly certain Pseudomonadota and Actinomycetota.
The atomic-resolution 3-dimensional structure of an SAH riboswitch has been solved using X-ray crystallography.