It occurs when a sound wave of sufficient intensity induces a gaseous cavity within a liquid to collapse quickly, emitting a burst of light.
In 1960, Peter Jarman proposed that sonoluminescence is thermal in origin and might arise from microshocks within collapsing cavities.
The exact mechanism behind sonoluminescence remains unknown, with various hypotheses including hotspot, bremsstrahlung, and collision-induced radiation.
Instead, they noticed tiny dots on the film after developing and realized that the bubbles in the fluid were emitting light with the ultrasound turned on.
[4] It was too difficult to analyze the effect in early experiments because of the complex environment of a large number of short-lived bubbles.
This technique allowed a more systematic study of the phenomenon because it isolated the complex effects into one stable, predictable bubble.
[9] Sonoluminescence can occur when a sound wave of sufficient intensity induces a gaseous cavity within a liquid to collapse quickly.
Using argon bubbles in sulfuric acid, the data shows the presence of ionized molecular oxygen O+2, sulfur monoxide, and atomic argon populating high-energy excited states, which confirms a hypothesis that the bubbles have a hot plasma core.
This equation, though approximate, has been shown to give good estimates on the motion of the bubble under the acoustically driven field except during the final stages of collapse.
[13] Thus a more detailed analysis of the bubble's motion is needed beyond Rayleigh–Plesset to explore the additional energy focusing that an internally formed shock wave might produce.
[citation needed] In 2002, M. Brenner, S. Hilgenfeldt, and D. Lohse published a 60-page review that contains a detailed explanation of the mechanism.
[14] An important factor is that the bubble contains mainly inert noble gas such as argon or xenon (air contains about 1% argon, and the amount dissolved in water is too great; for sonoluminescence to occur, the concentration must be reduced to 20–40% of its equilibrium value) and varying amounts of water vapor.
[15] The light emission of highly compressed noble gas is exploited technologically in the argon flash devices.
This description is simplified from the literature above, which details various steps of differing duration from 15 microseconds (expansion) to 100 picoseconds (emission).
Computations based on the theory presented in the review produce radiation parameters (intensity and duration time versus wavelength) that match experimental results[citation needed] with errors no larger than expected due to some simplifications (e.g., assuming a uniform temperature in the entire bubble), so it seems the phenomenon of sonoluminescence is at least roughly explained, although some details of the process remain obscure.
Experiments in 2002 and 2005 by R. P. Taleyarkhan using deuterated acetone showed measurements of tritium and neutron output consistent with fusion.
[27] It has subsequently been discovered that another group of crustaceans, the mantis shrimp, contains species whose club-like forelimbs can strike so quickly and with such force as to induce sonoluminescent cavitation bubbles upon impact.
[2] A mechanical device with 3D printed snapper claw at five times the actual size was also reported to emit light in a similar fashion,[28] this bioinspired design was based on the snapping shrimp snapper claw molt shed from an Alpheus formosus, the striped snapping shrimp.