Tritium

Tritium (from Ancient Greek τρίτος (trítos) 'third') or hydrogen-3 (symbol T or 3H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.3 years.

Tritium is used as the energy source in radioluminescent lights for watches, night sights for firearms, numerous instruments and tools, and novelty items such as self-illuminating key chains.

Beta particles from tritium can penetrate only about 6.0 millimetres (0.24 in) of air, and they are incapable of passing through the dead outermost layer of human skin.

The low energy of tritium's radiation makes it difficult to detect tritium-labeled compounds except by using liquid scintillation counting.

[11] Prior to this test, it was incorrectly assumed that 73Li would absorb a neutron to become 83Li, which would beta-decay to 84Be, which in turn would decay to two 42He nuclei on a total timeframe much longer than the duration of the explosion.

This reaction has a small absorption cross section, making heavy water a good neutron moderator, and relatively little tritium is produced.

India, which also has a large fleet of pressurized heavy water reactors (initially CANDU technology but since indigenized and further developed IPHWR technology), also removes at least some of the tritium produced in the moderator/coolant of its reactors but due to the dual use nature of tritium and the Indian nuclear bomb program, less information about this is publicly available than for Canada.

[18] Voloxidation is an optional additional step in nuclear reprocessing that removes volatile fission products (such as all isotopes of hydrogen) before an aqueous process begins.

The global equilibrium inventory of tritium created by natural sources remains approximately constant at 2,590 petabecquerels.

[30] Tritium for American nuclear weapons was produced in special heavy water reactors at the Savannah River Site until their closures in 1988.

With the Strategic Arms Reduction Treaty (START) after the end of the Cold War, the existing supplies were sufficient for the new, smaller number of nuclear weapons for some time.

This has raised concerns that if tritium were used in large quantities, in particular for fusion reactors, it might contribute to radioactive contamination, though its short half-life should prevent significant long-term accumulation in the atmosphere.

[45] H3HO has a short biological half-life in the human body of 7 to 14 days, which both reduces the total effects of single-incident ingestion and precludes long-term bioaccumulation of H3HO from the environment.

However, care should be taken that neither dehydration nor a depletion of the body's electrolytes results, as the health consequences of those things (particularly in the short term) can be more severe than those of tritium exposure.

In the extreme heat and pressure of the explosion, some of the tritium is then forced into fusion with deuterium, and that reaction releases even more neutrons.

During the operation of envisioned breeder fusion reactors, Breeding blankets, often containing lithium as part of ceramic pebbles, are subjected to neutron fluxes to generate tritium to complete the fuel cycle.

[57] The Tritium Systems Test Assembly (TSTA) was a facility at the Los Alamos National Laboratory dedicated to the development and demonstration of technologies required for fusion-relevant deuterium–tritium processing.

This ionization ensures reliable and consistent operation by providing a steady current when a high voltage is applied, enhancing the device's performance and stability.

Aside from chlorofluorocarbons, tritium can act as a transient tracer and can "outline" the biological, chemical, and physical paths throughout the world's oceans because of its evolving distribution.

[60][61][62] As noted earlier, nuclear tests, mainly in the Northern Hemisphere at high latitudes, throughout the late 1950s and early 1960s introduced lots of tritium into the atmosphere, especially the stratosphere.

Before these nuclear tests, there were only about 3-4 kg of tritium on the Earth's surface; but these amounts rose by 2-3 orders of magnitude during the post-test period.

[59] Some sources reported natural background levels were exceeded by about 1,000 TU in 1963 and 1964 and the isotope is used in the northern hemisphere to estimate the age of groundwater and construct hydrogeologic simulation models.

[59] Bomb-tritium data were used from the Transient Tracers in the Ocean (TTO) program in order to quantify the replenishment and overturning rates for deep water located in the North Atlantic.

[66] This NADW tends to spill over sills that divide the Norwegian Sea from the North Atlantic Ocean and then flows to the west and equatorward in deep boundary currents.

Also evident was the decrease in tritium in the deep western boundary current by a factor of 10 from the Labrador Sea to the Tropics, which is indicative of loss to ocean interior due to turbulent mixing and recirculation.

[68] Results indicated that the tritium concentration in surface seawater was highest at the Fremantle Bay (about 0.40 Bq/liter), which could be accredited to the mixing of runoff of freshwater from nearby lands due to large amounts found in coastal waters.

There were subsurface maxima in the middle and low latitude regions, which is indicative of lateral mixing (advection) and diffusion processes along lines of constant potential density (isopycnals) in the upper ocean.

[69] In order to obtain the structure for ocean circulation, the tritium concentrations were mapped on 3 surfaces of constant potential density (23.90, 26.02, and 26.81).

[69] The depth penetration of bomb tritium can be separated into three distinct layers: Trace amounts of radioactive materials from atomic weapons testing settled throughout the Mississippi River System.

Tritium concentrations have been used to understand the residence times of continental hydrologic systems such as lakes, streams, and rivers.

Radioluminescent 1.8 curies (67 GBq ) 6 by 0.2 inches (152.4 mm × 5.1 mm) tritium vials are thin, tritium-gas-filled glass vials whose inner surfaces are coated with a phosphor . The vial shown here is brand-new.
Partial tritiation of pyridine ( C 5 H 5 N ). The catalyst is not shown.
Swiss Military watch with tritium-illuminated face