Thermogravimetric analysis

A typical thermogravimetric analyzer consists of a precision balance with a sample pan located inside a furnace with a programmable control temperature.

It is an especially useful technique for the study of polymeric materials, including thermoplastics, thermosets, elastomers, composites, plastic films, fibers, coatings, paints, and fuels.

However, there is a class of thermally stable polymers that are able to withstand temperatures of at least 300 °C in air and 500 °C in inert gases without structural changes or strength loss, which can be analyzed by TGA.

For example, NASA (National Aeronautics and Space Administration) is conducting research on advanced copper alloys for their possible use in combustion engines.

One interesting example occurs with samples of as-produced unpurified carbon nanotubes that have a large amount of metal catalyst present.

[6][7] Thermogravimetric kinetics may be explored for insight into the reaction mechanisms of thermal (catalytic or non-catalytic) decomposition involved in the pyrolysis and combustion processes of different materials.

For example, the kinetic parameters of the carbonization of polyvinyl butyral were found using a constant mass loss rate of 0.2 wt %/min.

For example, the TGA instrument continuously weighs a sample as it is heated to temperatures of up to 2000 °C for coupling with Fourier-transform infrared spectroscopy (FTIR) and mass spectrometry gas analysis.

As the temperature increases, various components of the sample are decomposed and the weight percentage of each resulting mass change can be measured.