He worked at a teacher in Cernăuți, Craiova, Iași, Bucharest and he remained a bright personality of that epoch of formation for the Romanian modern educational system.
During the Revolution of 1848 he strengthened the link between the Walachian and Transylvanian revolutionaries and he activated as an agent of the Interim Govern, near the German Dieta from Frankfurt.
In the following number he intended to publish the translation of a short story written by Jean Paul and entitled "New Year's Eve Night".
The following year, he published his Philosophy essay entitled Philosophical Considerations for Everybody's Understanding (German: Einiges Philosophische in gemeinfasslicher Form) in Berlin, obviously under the influence of Herbart's and Feuerbach's ideas.
In order to complete this mission, commissioned by the Minister of Public Directions from back then, Alexandru Odobescu, he traveled on a documentary journey to Berlin and later he returned to Iași on 4 January 1864.
On 10 March 1861, Titu Maiorescu held a lecture (Die alte französische Tragödie und die Wagnersche Musik — „The Old French Tragedy and Wagner's Music”) in Berlin for the benefit of the monument of Lessing from Kamenz, which he repeated on 12 April in Paris, at the „Cercle des sociétés savantes“ (Circle of Academic Societies) and later renewed in the form of a communication, on 27 April in Berlin, at the Philosophy Society.
When he returned to Romania, at the end of 1861, Titu Maiorescu was eager to contribute to the progress of the recently formed state, after the Union of 1859, of the cultural and political life, of a European level.
At that time, when the Union was done and personalities of fresh energies and cultured people were needed, people who were educated in Western Universities, Titu Maiorescu had an early ascent, from his youth, as he was a university professor at 22 years old (in Iași), a dean at 23 and a rector at the same age, then he became an academician (member of the Romanian Academic Society) at 27, a deputy at 30, then a minister at age 34.
But this ascent was not always smooth or without hardships, as he was once sued because of all the calumnies that his political opponents promoted and he was suspended from all his functions in 1864, but the verdict of discharge from the following year proved the baselessness of all the accusation against him.
He started his work as a lawyer, then he was elected principal of the School „Vasile Lupu“ from Iași, and then he founded the a review Convorbiri Literare in 1867.
Although the period that followed after the Union of 1859 represented an epoch of completion of the ideals of the generation of 1848, a few accents still had changed, the conditions were different from the romantic youth of Heliade Rădulescu, Alecsandri or Bălcescu.
On the political ideology plan, Maiorescu was a retentionist, an advocate of a natural, organic and well prepared evolution and an adversary of the „forms without root“, whose indictment he made in his article from 1868, Against nowadays direction in Romanian culture, in which he criticized the implementation of certain institutions which were imitated after the Western ones and to which no appropriate root corresponded in the mentalitaty, creation and cultural legacy of the Romanian people.
Unlike the previous years of the revolution from 1848, when an intense need of original literature determined Heliade Rădulescu to address enthusiastic appeals for Romanian literary works, the seventh decade of the 19th century was marked by a large number of poets and prosemen, who had very limited artistical devices, but high ideals and pretences.
The adversaries of his ideas depreciatively called his action „a judicial criticism“, because his studies and articles did not analyse in detail the literary work that they had discussed and they contain many apothegms on it.
The mentor of Junimea society considered this type of criticism (neatly affirmative or negative) necessary only to that epoch of clutter of values, as its modalities of execution would gradate later, in the literary life, when the great writers would elevate the artistic level and implicitly would have the public's exigency augmented.
This work as a tutor, as fighter for the assertion of values, would be led by Maiorescu throughout his entire life and would be divided between his political activity (he would become prime minister, but he will lose a friend from his youth, P.P.
The role of Junimea society and of Maiorescu himself is linked to the creation and the assertion in the public's conscience of writers like Eminescu, Creangă, Caragiale, Slavici, Duiliu Zamfirescu and others.
The help that Maiorescu gave to the writers from the circle of Junimea and to his disciples and even to his adversary, Dobrogeanu-Gherea, in an important moment of his life, unfolded a man of great and at the same time discreet generosity.