In 2000, with a 20-game stint with the Cape Fear Crocs, the Single-A affiliate of the Expos, Pascucci batted .319 with 3 home runs and 10 RBI and was called up to the High-A Jupiter Hammerheads later that season.

Val was promoted to the Double-A Harrisburg Senators for the 2002 season, where he sent a minor league career high 27 home runs out of the park.

On April 6, 2007, Pascucci was signed by the Florida Marlins and spent the season with their Triple-A affiliate, the Albuquerque Isotopes.

In December 2007, Pascucci signed a minor league contract with the Philadelphia Phillies' Triple-A affiliate, the Lehigh Valley IronPigs.

After being released by the Phillies on April 29, Pascucci signed a minor league contract with the New York Mets a few days later.

Pascucci was signed by the San Diego Padres on June 27, 2009, and assigned to their Triple-A affiliate, the Portland Beavers.

On May 14, 2010, after a brief stint with the Camden Riversharks, Pascucci signed a minor league deal with the New York Mets, and was assigned to the Triple-A Buffalo Bisons.

During the 2012 season, Pascucci got invited to the Triple-A All-Star Game and Home Run Derby held in Buffalo, New York.

Pascucci was named as the hitting coach for the Binghamton Rumble Ponies of the New York Mets organization for the 2018 season.