She graduated with a thesis on the economy of labor and the gender issue in Saudi Arabia after the Gulf crisis from the University of Bologna.
[1] She is the granddaughter of Francesco Berti, one of the founders of the Sammarinese Communist Party.
D'Ambrosio is the second youngest woman who became Captain Regent in the history of San Marino after Maria Lea Pedini-Angelini, who was sworn in at the age of 25.
Since December 2016, D'Ambrosio has been the Head of Delegation for San Marino to the Council of Europe.
She participated in the Strasbourg Plenary Session in January 2017, where she signed a motion for the protection of migrant children through education.