Vinegar syndrome

[4] It has also been observed to affect older magnetic tape, where cellulose acetate is used as a base, as well as polarizers used in liquid-crystal display units and everyday plastics such as containers and tableware.

[3][4] The first instance of cellulose triacetate degradation was reported to the Eastman Kodak Company within a decade of its introduction in 1948.

[9] In acetate film, acetyl (CH3CO) groups are attached to long molecular chains of cellulose.

[10] While the acid is initially released inside the plastic, it gradually diffuses to the surface, causing a characteristic vinegary smell.

The decay process follows this pattern: A testing product developed by the Image Permanence Institute, A-D, or "acid-detection" indicator strips change color from blue through shades of green to yellow with increasing exposure to acid.

Shrinking and warpage of 16 mm film caused by vinegar syndrome
Bubbling and warpage of a laptop's LCD polarizer caused by vinegar syndrome