[1][2][3] She is best known for her roles as Zhou Jiamin on How Much Sorrow Do You Have, Princess Weichang on The Prince of Han Dynasty Part 3: Iron Blood and the Pages of History and Cong Hui on Ice and Fire of Youth, and has also starred in a number of films, including The First President, Tai Chi 0, Tai Chi Hero, The Deathday Party, and Ex-Files.
In 2003, when she was a freshman at Beijing Film Academy, Xiong made her acting debut in Crime Scene, playing a policewoman.
In 2005, she had a key supporting role in the historical television series The Prince of Han Dynasty, playing the daughter (Princess Weichang) of Huang Xiaoming's and Ruping's characters.
[6] In 2006, she was cast in the lead role of Wulan in the wuxia television series Big Shots, based on the novel by the same name by Gu Long.
She played the female lead role in Li Qilin's romantic comedy film Rhapsody of BMW.
[23] The same year, she guest-starred on the fantasy series Noble Aspirations playing Youji, one of four great messengers of the Ghost King Faction.
[24] In 2016, Xiong Naijin had a key supporting role in Phoenix Warriors, a fantasy television series adaptation based on the novel Meiren Mou by Bing Lansha.