1,2-Cyclopentanedione

1,2-Cyclopentanedione is the organic compound with the formula (CH2)3(CO)2.

It was first prepared by base-induced condensation of di ethylglutarate with diethyloxalate, followed by hydrolysis of the resulting diketodiester followed by decarboxylation.

[1] The enol is predicted to be about 1-3 kcal/mol more stable than the diketo form.

[2] The enol structure has been confirmed by X-ray crystallography.

[3] Structurally related to 1,2-cyclopentanedione is 2-hydroxy-3-methyl-2-cyclopenten-1-one is a flavor additive, also called cyclotene.