The team played in the domestic league, as well as the Copa de la Reina, the Supercopa de España, and UEFA Women's Champions League.

Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.

Source: FC Barcelona[1] Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply.

Following the abandonment of the 2019–20 Primera División due to the COVID-19 pandemic, Barcelona and Atlético Madrid were selected by the RFEF to take the two Spain slots in the next year's Champions League.

Due to Spain's high ranking, both teams entered in the knockout phase (round of 32), rather than go through qualifying.