It is a charge-transfer process by which normal current in N is converted to supercurrent in S. Each Andreev reflection transfers a charge 2e across the interface, avoiding the forbidden single-particle transmission within the superconducting energy gap.
The process is highly spin-dependent – if only one spin band is occupied by the conduction electrons in the normal-state material (i.e. it is fully spin-polarized), Andreev reflection will be inhibited due to inability to form a pair in the superconductor and impossibility of single-particle transmission.
By applying a voltage to the tip, and measuring differential conductance between it and the sample, the spin polarization of the normal metal at that point (and magnetic field) may be determined.
This is of use in such tasks as measurement of spin-polarized currents or characterizing spin polarization of material layers or bulk samples, and the effects of magnetic fields on such properties.
Crossed Andreev reflection occurs in competition with elastic cotunneling, the quantum mechanical tunneling of electrons between the normal leads via an intermediate state in the superconductor.