It states that a labiovelar stop (*kʷ, *gʷ, *gʷʰ) dissimilates to an ordinary velar stop (*k, *g, *gʰ) next to the vowel *u or its corresponding glide *w. The rule is named after an example, the Ancient Greek word βουκόλος (bou-kólos; from Mycenaean Greek qo-u-ko-ro /ɡʷou̯kolos/[1]) "cowherd", ultimately from PIE *gʷou-kolos, dissimilated from *gʷou-kʷolos.
If the labiovelar had not undergone dissimilation, the word should have turned out as *bou-pólos, as in the analogously constructed αἰπόλος (ai-pólos) "goatherd" < *ai(ǵ)-kʷolos.
[2]: 64 The same dissimilated form *gʷou-kolos is the ancestor of Proto-Celtic *bou-koli-, the source of Welsh bugail (which would have had -b- rather than -g- if it had come from a form with *-kʷ-) and Irish buachaill, which is the common word for "boy" in the modern language.
[3]: 72 Another example could be the Greek negation οὐκ[ί] (ouk[í]), which Warren Cowgill has interpreted as coming from pre-Greek *ojukid < *(ne) h₂oju kʷid, meaning approximately "not on your life".
[2]: 133 The rule is also found in Germanic, mainly in verbs, where labiovelars are delabialised by the epenthetic -u- inserted before syllabic resonants:[4]: 111–112 This article about historical linguistics is a stub.