Cohesion (chemistry)

It is an intrinsic property of a substance that is caused by the shape and structure of its molecules, which makes the distribution of surrounding electrons irregular when molecules get close to one another, creating electrical attraction that can maintain a macroscopic structure such as a water drop.

Cohesion allows for surface tension, creating a "solid-like" state upon which light-weight or low-density materials can be placed.

Cohesion, along with adhesion (attraction between unlike molecules), helps explain phenomena such as meniscus, surface tension and capillary action.

Mercury in a glass flask is a good example of the effects of the ratio between cohesive and adhesive forces.

Because of its high cohesion and low adhesion to the glass, mercury does not spread out to cover the bottom of the flask, and if enough is placed in the flask to cover the bottom, it exhibits a strongly convex meniscus, whereas the meniscus of water is concave.