Perhaps the most pivotal release in Divino's career was the song Quiero Saber, which he recorded for the compilation album MVP which sold over 100,000 copies in 2002.
In 2003, he released his solo album Todo A Su Tiempo, which included such hits as the Daddy Yankee collaboration Se Activaron Los Anormales, Super Gangsteril featuring Polaco, Ya Estoy Llegando, and the ballad Dile Mar.
Divino briefly was a part of the label Drama Records owned by Ivy Queen from 2007 to 2008 where he released one single "Pobre Corazón" for her album Sentimiento (2007).
Todo A Su Tiempo achieved gold status and Divino earned two nominations for the 2004 Billboard Awards: one for Best New Artist and another for Best Tropical Album.
With reggaetón earning international acclaim and Divino poised for even greater success, MVP Records released Todo A Su Tiempo: Platinum Edition in 2006.