Donnan potential is the difference in the Galvani potentials[1] which appears as a result of Donnan equilibrium, named after Frederick G. Donnan, which refers to the distribution of ion species between two ionic solutions separated by a semipermeable membrane or boundary.
[2] The boundary layer maintains an unequal distribution of ionic solute concentration by acting as a selective barrier to ionic diffusion.
Some species of ions may pass through the barrier while others may not.
Donnan equilibrium is prominent in the triphasic model for articular cartilage proposed by Mow and Ratcliffe, as well as in electrochemical fuel cells and dialysis.
The Donnan effect is extra osmotic pressure attributable to cations (Na+ and K+) attached to dissolved plasma proteins.