Chemical element

Much of the modern understanding of elements developed from the work of Dmitri Mendeleev, a Russian chemist who published the first recognizable periodic table in 1869.

[6] On Earth, small amounts of new atoms are naturally produced in nucleogenic reactions, or in cosmogenic processes, such as cosmic ray spallation.

At over 1.9×1019 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope, and is almost always considered on par with the 80 stable elements.

The first 94 elements have been detected directly on Earth as primordial nuclides present from the formation of the Solar System, or as naturally occurring fission or transmutation products of uranium and thorium.

Different isotopes of a given element are distinguished by their mass number, which is written as a superscript on the left hand side of the chemical symbol (e.g., 238U).

Whenever a relative atomic mass value differs by more than ~1% from a whole number, it is due to this averaging effect, as significant amounts of more than one isotope are naturally present in a sample of that element.

Several kinds of descriptive categorizations can be applied broadly to the elements, including consideration of their general physical and chemical properties, their states of matter under familiar conditions, their melting and boiling points, their densities, their crystal structures as solids, and their origins.

A first distinction is between metals, which readily conduct electricity, nonmetals, which do not, and a small group, (the metalloids), having intermediate properties and often behaving as semiconductors.

Another commonly used basic distinction among the elements is their state of matter (phase), whether solid, liquid, or gas, at standard temperature and pressure (STP).

Chemical elements may also be categorized by their origin on Earth, with the first 94 considered naturally occurring, while those with atomic numbers beyond 94 have only been produced artificially via human-made nuclear reactions.

Of these 11 transient elements, five (polonium, radon, radium, actinium, and protactinium) are relatively common decay products of thorium and uranium.

For example, at over 1.9×1019 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope.

Although earlier precursors to this presentation exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869, who intended the table to illustrate recurring trends in the properties of the elements.

The layout of the table has been refined and extended over time as new elements have been discovered and new theoretical models have been developed to explain chemical behavior.

Use of the periodic table is now ubiquitous in chemistry, providing an extremely useful framework to classify, systematize and compare all the many different forms of chemical behavior.

The table has also found wide application in physics, geology, biology, materials science, engineering, agriculture, medicine, nutrition, environmental health, and astronomy.

In the second half of the 20th century, physics laboratories became able to produce elements with half-lives too short for an appreciable amount of them to exist at any time.

With his advances in the atomic theory of matter, John Dalton devised his own simpler symbols, based on circles, to depict molecules.

Other languages sometimes modify element name spellings: Spanish iterbio (ytterbium), Italian afnio (hafnium), Swedish moskovium (moscovium); but those modifications do not affect chemical symbols: Yb, Hf, Mc.

Also, three primordially occurring but radioactive actinides, thorium, uranium, and plutonium, decay through a series of recurrently produced but unstable elements such as radium and radon, which are transiently present in any sample of containing these metals.

As physical laws and processes appear common throughout the visible universe, however, scientists expect that these galaxies evolved elements in similar abundance.

The abundance of elements in the Solar System is in keeping with their origin from nucleosynthesis in the Big Bang and a number of progenitor supernova stars.

Elements heavier than iron are made in energy-absorbing processes in large stars, and their abundance in the universe (and on Earth) generally decreases with their atomic number.

Aluminium at 8% by mass is more common in the Earth's crust than in the universe and solar system, but the composition of the far more bulky mantle, which has magnesium and iron in place of aluminium (which occurs there only at 2% of mass) more closely mirrors the elemental composition of the solar system, save for the noted loss of volatile elements to space, and loss of iron which has migrated to the Earth's core.

Certain kinds of organisms require particular additional elements, for example the magnesium in chlorophyll in green plants, the calcium in mollusc shells, or the iron in the hemoglobin in vertebrates' red blood cells.

The term 'elements' (stoicheia) was first used by Greek philosopher Plato around 360 BCE in his dialogue Timaeus, which includes a discussion of the composition of inorganic and organic bodies and is a speculative treatise on chemistry.

Plato believed the elements introduced a century earlier by Empedocles were composed of small polyhedral forms: tetrahedron (fire), octahedron (air), icosahedron (water), and cube (earth).

[47]Even though Boyle is primarily regarded as the first modern chemist, The Sceptical Chymist still contains old ideas about the elements, alien to a contemporary viewpoint.

Currently, IUPAC defines an element to exist if it has isotopes with a lifetime longer than the 10−14 seconds it takes the nucleus to form an electronic cloud.

Ten materials familiar to various prehistoric cultures are now known to be elements: Carbon, copper, gold, iron, lead, mercury, silver, sulfur, tin, and zinc.

The chemical elements ordered in the periodic table
Estimated distribution of dark matter and dark energy in the universe. Only the fraction of the mass and energy labeled "atoms" is composed of elements.
Periodic table showing the cosmogenic origin of each element in the Big Bang, or in large or small stars. Small stars can produce certain elements up to sulfur, by the alpha process . Supernovae are needed to produce "heavy" elements (those beyond iron and nickel) rapidly by neutron buildup, in the r-process . Certain large stars slowly produce other elements heavier than iron, in the s-process ; these may then be blown into space in the off-gassing of planetary nebulae
Abundances of the chemical elements in the Solar System. Hydrogen and helium are most common, from the Big Bang. The next three elements (Li, Be, B) are rare because they are poorly synthesized in the Big Bang and also in stars. The two general trends in the remaining stellar-produced elements are: (1) an alternation of abundance in elements as they have even or odd atomic numbers (the Oddo–Harkins rule ), and (2) a general decrease in abundance as elements become heavier. Iron is especially common because it represents the minimum energy nuclide that can be made by fusion of helium in supernovae.
Robert Boyle, c. 1740
Title page of The Sceptical Chymist, published in 1661
Portrait of Isaac Watts by John Shury, c. 1830
Mendeleev 's 1869 periodic table: An experiment on a system of elements. Based on their atomic weights and chemical similarities.
Dmitri Mendeleev, 1897