The field effect underlies the operation of the Schottky diode and of field-effect transistors, notably the MOSFET, the JFET and the MESFET.
A typical treatment of such effects is based upon a band-bending diagram showing the positions in energy of the band edges as a function of depth into the material.
The example in the figure shows the Fermi level in the bulk material beyond the range of the applied field as lying close to the valence band edge.
In this case the impurities are so-called acceptors which soak up electrons from the valence band becoming negatively charged, immobile ions embedded in the semiconductor material.
In the semiconductor at the smaller voltage shown in the top panel, the positive charge placed on the left face of the insulator lowers the energy of the valence band edge.
Consequently, these states are fully occupied out to a so-called depletion depth where the bulk occupancy reestablishes itself because the field cannot penetrate further.