Hard hexagon model

The hard hexagon model occurs within the framework of the grand canonical ensemble, where the total number of particles (the "hexagons") is allowed to vary naturally, and is fixed by a chemical potential.

In the hard hexagon model, all valid states have zero energy, and so the only important thermodynamic control variable is the ratio of chemical potential to temperature μ/(kT).

The exponential of this ratio, z = exp(μ/(kT)) is called the activity and larger values correspond roughly to denser configurations.

Solving the hard hexagon model means (roughly) finding an exact expression for κ as a function of z.

The mean density ρ is given for small z by The vertices of the lattice fall into 3 classes numbered 1, 2, and 3, given by the 3 different ways to fill space with hard hexagons.

The hard hexagon model can be defined similarly on the square and honeycomb lattices.