Lithography (from Ancient Greek λίθος (líthos) 'stone' and γράφω (gráphō) 'to write')[1] is a planographic method of printing originally based on the immiscibility of oil and water.
Traditionally, the image to be printed was drawn with a greasy substance, such as oil, fat, or wax onto the surface of a smooth and flat limestone plate.
[6] In modern commercial lithography, the image is transferred or created as a patterned polymer coating applied to a flexible plastic or metal plate.
The image is drawn on the surface of the print plate with a fat or oil-based medium (hydrophobic) such as a wax crayon, which may be pigmented to make the drawing visible.
A wide range of oil-based media is available, but the durability of the image on the stone depends on the lipid content of the material being used, and its ability to withstand water and acid.
The function of this solution is to create a hydrophilic layer of calcium nitrate salt, Ca(NO3)2, and gum arabic on all non-image surfaces.
[1] The gum solution penetrates into the pores of the stone, completely surrounding the original image with a hydrophilic layer that will not accept the printing ink.
Using lithographic turpentine, the printer then removes any excess of the greasy drawing material, but a hydrophobic molecular film of it remains tightly bonded to the surface of the stone, rejecting the gum arabic and water, but ready to accept the oily ink.
[citation needed] Senefelder had experimented during the early 19th century with multicolor lithography; in his 1819 book, he predicted that the process would eventually be perfected and used to reproduce paintings.
This method lent itself to images consisting of large areas of flat color, and resulted in the characteristic poster designs of this period.
[citation needed] "Lithography, or printing from soft stone, largely took the place of engraving in the production of English commercial maps after about 1852.
"[12] High-volume lithography is used to produce posters, maps, books, newspapers, and packaging—just about any smooth, mass-produced item with print and graphics on it.
[citation needed] For offset lithography, which depends on photographic processes, flexible aluminum, polyester, mylar or paper printing plates are used instead of stone tablets.
Instead, the plate rolls against a cylinder covered with a rubber blanket, which squeezes away the water, picks up the ink and transfers it to the paper with uniform pressure.
Recent dampening systems include a "delta effect or vario", which slows the roller in contact with the plate, thus creating a sweeping movement over the ink image to clean impurities known as "hickies".
During the early years of the 19th century, lithography had only a limited effect on printmaking, mainly because technical difficulties remained to be overcome.
Godefroy Engelmann, who moved his press from Mulhouse to Paris in 1816, largely succeeded in resolving the technical problems, and during the 1820s lithography was adopted by artists such as Delacroix and Géricault.
By the mid-century the initial enthusiasm had somewhat diminished in both countries, although the use of lithography was increasingly favored for commercial applications, which included the prints of Daumier, published in newspapers.
[15][16] Grant Wood, George Bellows, Alphonse Mucha, Max Kahn, Pablo Picasso, Eleanor Coen, Jasper Johns, David Hockney, Susan Dorothea White, and Robert Rauschenberg are a few of the artists who have produced most of their prints in the medium.