From 2019 to 2023, during the government of Alberto Fernández, Volnovich served as the executive director of the Comprehensive Medical Attention Program (PAMI), Argentina's biggest public health insurance agency.

Luana Volnovich was born on 26 September 1979 in Rio de Janeiro, Brazil to Argentine parents exiled during the last civic–military dictatorship in Argentina (1976–1983).

[2][3] She also has a post-graduate degree in Public Policy Administration and Control from the Latin American Faculty of Social Sciences (FLACSO).

[7][8] At the 2015 legislative elections, Volnovich was the 12th candidate in the Front for Victory list to the Argentine Chamber of Deputies in Buenos Aires Province.

[11] As deputy, Volnovich voted against the Mauricio Macri administration's pension reform in 2017, and introduced a bill to overturn it after it had passed the Chamber.