[1] Unlike ferrocene, magnesocene displays slight dissociation and subsequent ion association in polar, electron-donating solvents (such as ether and THF).
[4] Gas-phase electron diffraction has shown similar bond lengths, albeit with the Cp rings in an eclipsed conformation (point group D5h).
The weak nature of this bonding mode is responsible for magnesocene's relative instability and vigorous reactivity when compared to ferrocene.
[1] Under water- and oxygen-free conditions, freshly distilled monomeric cyclopentadiene is directed through a tube furnace by an inert carrier gas (such as helium, argon, or nitrogen) and passed over magnesium turnings or powder.
The product of this process is typically a white, fluffy mass of fine microcrystals, but large, colorless single crystals can be obtained by adjusting temperature and flow rate.
[14] Because of its high reactivity, magnesocene is an attractive target for semiconductor research as a starting material for chemical vapor deposition and doping applications.