Molecular electronics

It provides a potential means to extend Moore's Law beyond the foreseen limits of small-scale conventional silicon integrated circuits.

Because single molecules constitute the smallest stable structures possible, this miniaturization is the ultimate goal for shrinking electrical circuits.

However, the continuous demand for more computing power, together with the inherent limits of the present day lithographic methods make the transition seem unavoidable.

Currently, the focus is on discovering molecules with interesting properties and on finding ways to obtain reliable and reproducible contacts between the molecular components and the bulk material of the electrodes.

The significant amount of energy due to charging has to be taken into account when making calculations about the electronic properties of the setup and is highly sensitive to distances to conducting surfaces nearby.

Because the current photolithographic technology is unable to produce electrode gaps small enough to contact both ends of the molecules tested (in the order of nanometers), alternative strategies are used.

[3] Another method is to use the tip of a scanning tunneling microscope (STM) to contact molecules adhered at the other end to a metal substrate.

[6] One of the biggest hindrances for single-molecule electronics to be commercially exploited is the lack of means to connect a molecular sized circuit to bulk electrodes in a way that gives reproducible results.

Nevertheless, conducting polymers are rapidly gaining attraction in new uses with increasingly processable materials with better electrical and physical properties and lower costs.

[9] Newer nanostructured forms of conducting polymers provide fresh impetus to this field, with their higher surface area and better dispersability.

Graphical representation of a rotaxane , useful as a molecular switch
Chemical structures of some conductive polymers. From top left clockwise: polyacetylene ; polyphenylene vinylene ; polypyrrole (X = NH) and polythiophene (X = S); and polyaniline (X = NH/N) and polyphenylene sulfide (X = S).